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Monday, April 20, 2009

NUCLEAR REACTION

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In nuclear physics, a nuclear reaction is the process in which two nuclei or nuclear particles collide to produce products different from the initial particles. In principle a reaction can involve more than three particles colliding, but because the probability of three or more nuclei to meet at the same time at the same place is much less than for two nuclei, such an event is exceptionally rare. While the transformation is spontaneous in the case of radioactive decay, it is initiated by a particle in the case of a nuclear reaction. If the particles collide and separate without changing, the process is called an elastic collision rather than a reaction.
In the symbolic figure shown to the right, 63Li and deuterium react to form the highly excited intermediate nucleus 84Be which then decays immediately into two alpha particles. Protons are symbolically represented by red spheres, and neutrons by blue spheres.
63Li + 21H → 42He + ?
To make the sums correct, the second nucleus to the right must have atomic number 2 and mass number 4; it is therefore also Helium-4. The complete equation therefore reads:
63Li + 21H → 42He + 42He
or more simply:
63Li + 21H → 2 42He
1. Notation
Instead of using the full equations as shown in the previous section, in many situations a compact notation is used to describe nuclear reactions. This is A(b,c)D, which is equivalent to A + b gives c + D. Common light particles are often abbreviated in this shorthand, typically p for proton, n for neutron, α representing an alpha particle or Helium-4, etc. The reaction above would be written as Li-6(d,α)α.
2. Energy conservation
Kinetic energy may be released during the course of a reaction (exothermic reaction) or kinetic energy may have to be supplied for the reaction to take place (endothermic reaction). This can be calculated by reference to a table of very accurate particle rest masses (see http://physics.nist.gov/PhysRefData/Compositions/index.html), as follows. According to the reference tables, the 63Li nucleus has a relative atomic mass of 6.015 atomic mass units (abbreviated u), the deuterium has 2.014 u, and the helium-4 nucleus has 4.0026 u Thus:
• Total rest mass on left side = 6.015 + 2.014 = 8.029 u
• Total rest mass on right side = 2 × 4.0026 = 8.0052 u
• Missing rest mass = 8.029 - 8.0052 = 0.0238 atomic mass units.
In a nuclear reaction, the total (relativistic) energy is conserved. The "missing" rest mass must therefore reappear as kinetic energy released in the reaction; its source is the nuclear binding energy. Using Einstein's mass-energy equivalence formula E = mc², the amount of energy released can be determined. We first need the energy equivalent of one atomic mass unit:
1 u c2 = (1.66054 × 10-27 kg) × (2.99792 × 108 m/s)2
= 1.49242 × 10-10 kg (m/s)2 = 1.49242 × 10-10 J (Joule)
× (1 MeV / 1.60218 × 10-13 J)
= 931.49 MeV,
so 1 u c2 = 931.49 MeV.
Hence, the energy released is 0.0238 × 931 MeV = 22.4 MeV.
Expressed differently: the mass is reduced by 0.3 %, corresponding to 0.3 % of 90 PJ/kg is 300 TJ/kg.
This is a large amount of energy for a nuclear reaction; the amount is so high because the binding energy per nucleon of the helium-4 nucleus is unusually high, because the He-4 nucleus is doubly magic. (The He-4 nucleus is unusually stable and tightly-bound for the same reason that the helium atom is inert: each pair of protons and neutrons in He-4 occupies a filled 1s nuclear orbital in the same way that the pair of electrons in the helium atom occupy a filled 1s electron orbital). Consequently, alpha particles appear frequently on the right hand side of nuclear reactions.
The energy released in a nuclear reaction can appear mainly in one of three ways:
• kinetic energy of the product particles
• emission of very high energy photons, called gamma rays
• some energy may remain in the nucleus, as a metastable energy level.
When the product nucleus is metastable, this is indicated by placing an asterisk ("*") next to its atomic number. This energy is eventually released through nuclear decay.
A small amount of energy may also emerge in the form of X-rays. Generally, the product nucleus has a different atomic number, and thus the configuration of its electron shells is wrong. As the electrons rearrange themselves and drop to lower energy levels, internal transition X-rays (X-rays with precisely defined emission lines) may be emitted.
en.wikipedia.org

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